Exploiting recognition-mediated assembly and reactivity in [2]rotaxane formation† †Electronic supplementary information (ESI) available: Details of kinetic experiments, computational methods and characterisation data for all compounds are provided. See DOI: 10.1039/c5sc04805b Click here for additional data file.

pH controlled assembly of a self-complementary halogen-bonded dimer† †Electronic supplementary information (ESI) available: Details of computational methods, synthesis and characterisation data for all compounds are provided. CCDC 1488032–1488035. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6sc03696a Click here for additional data file. Click here for additional data file.

Neutral iodotriazoles as scaffolds for stable halogen-bonded assemblies in solution† †Electronic supplementary information (ESI) available: Details of computational methods, synthesis and characterisation data for all compounds are provided. CCDC 1442418–1442421. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6sc01974a Click here for additional data file.

School of Chemistry and EaStCHEM, Un Andrews, Fife KY16 9ST, UK. E-mail: d.ph 463808; Tel: +44 (0)1334 467264 Institut de Génétique et de Biologie Molécu UMR 7104, Université de Strasbourg, Graffenstaden, France † Electronic supplementary information ( methods, synthesis and characterisation CCDC 1442418–1442421. For ESI and c electronic format see DOI: 10.1039/c6sc01 Cite this: Chem. Sci., 201...

Competitive formation of homocircuit [3]rotaxanes in synthetically useful yields in the bipyridine-mediated active template CuAAC reaction† †Electronic supplementary information (ESI) available: Full experimental details and characterisation of all novel compounds. See DOI: 10.1039/c4sc03999h Click here for additional data file.

Enantioselective Narasaka–Heck cyclizations: synthesis of tetrasubstituted nitrogen-bearing stereocenters† †Electronic supplementary information (ESI) available: Experimental procedures and characterisation data for all compounds are provided. CCDC 1438659 and 1438660. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6sc04466b Click here for additional data file. Click here for additional data file.

School of Chemistry, University of Bristol, B bris.ac.uk AstraZeneca, Alderley Park, Maccleseld, C AstraZeneca, Pepparedsleden 1, Mölndal, 4 † Electronic supplementary information ( and characterisation data for all compou 1438660. For ESI and crystallographic dat DOI: 10.1039/c6sc04466b ‡ These authors contributed equally. § Author to whom correspondence shou structures of 3b and Pd[(Sa,S)-L-...

Synthesis of malhamensilipin A exploiting iterative epoxidation/chlorination: experimental and computational analysis of epoxide-derived chloronium ions† †Electronic supplementary information (ESI) available. CCDC 1470484 and 1470483. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6sc03012b Click here for additional data file. Click here for additional data file.